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Extraction of carrier-free 99Mo by ionic liquids from acid solutions: A model of seaborgium (Sg) experiment

Authors :
I.M. Ahmed
Mohamed F. Attallah
H. F. Aly
A.I. Abd-Elhamid
Source :
Applied Radiation and Isotopes. 149:83-88
Publication Year :
2019
Publisher :
Elsevier BV, 2019.

Abstract

A new approach for extraction of 99Mo tracer as a lighter homolog of Seaborgium (Sg) by three different the ionic liquids are studied. Aliquat-336 [Aliq-336.Cl-] as anion exchange has been used for the preparation of three ionic liquid, namely: ([Aliq-336]+ [SCN]-), ([Aliq-336]+ [S]- ) and ([Aliq-336]+ [Fe(CN)6]-). Their potential extraction of carrier free 99Mo from HNO3 solutions has been evaluated. The obtained results demonstrated that successful extraction of carrier free 99Mo from HNO3 solutions is achieved. The ([Aliq-336]+ [Fe(CN)6]-) is found to give the highest extraction affinity for 99Mo than the others ionic liquids investigated. The preliminary results could be useful for the upcoming aqueous experiments of Seaborgium.

Details

ISSN :
09698043
Volume :
149
Database :
OpenAIRE
Journal :
Applied Radiation and Isotopes
Accession number :
edsair.doi...........eabb368b806dd32c9e008c9d8b4be321
Full Text :
https://doi.org/10.1016/j.apradiso.2019.04.020