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A 3D inorganic-organic hybrid constructed from Strandberg-type polyoxometalates and silver complexes: Synthesis, structure and properties
- Source :
- Inorganic Chemistry Communications. 102:104-107
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- A 3D Strandberg-type polyoxometalate-based inorganic-organic hybrid, [Ag4(H3L)2(P2Mo5O23)]·H2O (1) (H2L = 2,6-dimethyl-3,5-bis(pyrazol-3-yl)pyridine), has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction, elemental analysis, IR, TG and powder X-ray diffraction. In compound 1, the adjacent [P2Mo5O23]6− clusters are linked by Ag1 into a 2D layer with left- and right-handed helical chains. And the layers are further linked together through organic ligands H2L and Ag⋯Ag interactions into a 3D framework with 1D channels extended along c axis. The luminescence, electrochemical properties and photocatalytic activities of compound 1 have also been investigated.
- Subjects :
- Diffraction
Materials science
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Electrochemistry
01 natural sciences
Hydrothermal circulation
0104 chemical sciences
Inorganic Chemistry
Crystallography
chemistry.chemical_compound
chemistry
Polyoxometalate
Pyridine
Materials Chemistry
Photocatalysis
Physical and Theoretical Chemistry
0210 nano-technology
Luminescence
Single crystal
Subjects
Details
- ISSN :
- 13877003
- Volume :
- 102
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........eadb9d6a7a774f18e34d19de699ae7f6