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Nature and catalytic performance of PtSAPO-5 molecular sieve catalyst synthesized by one step
- Source :
- Korean Journal of Chemical Engineering. 15:505-509
- Publication Year :
- 1998
- Publisher :
- Springer Science and Business Media LLC, 1998.
-
Abstract
- Pt catalysts supported on silicoaluminophosphate molecular sieves were synthesized by adding platinum salts directly to the gel mixture of SAPO. The synthesized products were marked as PtSAPO-5, in order to distinguish with the SAPO-5 supported platinum catalyst prepared by impregnation, which was marked as Pt/SAPO-5. The as-synthesized and calcined PtSAPO-5 samples were characterized by XRD,29Si MAS NMR,129XeNMR and NH3-TPD, and their catalytic activities were evaluated by the hydroisomerization of n-hexane. The results revealed that in PtSAPO-5, the platinum could catalyze the removal of the templates entrapped in the as-synthesized samples. The presence of Pt in the gel mixture can increase silicon content in the framework of SAPO-5, and the acid sites. In the activated PtSAPO-5 catalyst, Pt was highly dispersed in the channel of SAPO-5 molecular sieve. Pt exists in the form of big particles outside of the channel of Pt/SAPO-5 prepared by impregnating method, and impregnation with H2PtCl6 improved the strength of acid sites. PtSAPO-5 has a higher activity and selectivity than Pt/SAPO-5 in the hydroisomerization of n-hexane. This is because the former has medium acid sites and high dispersion of Pt, while the channel of Pt/SAPO-5 is somewhat retarded by the big platinum particles, and the acid sites are stronger than the former.
Details
- ISSN :
- 19757220 and 02561115
- Volume :
- 15
- Database :
- OpenAIRE
- Journal :
- Korean Journal of Chemical Engineering
- Accession number :
- edsair.doi...........ec3f027b389ad690ae93b5f72bf886de