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ChemInform Abstract: Regioselective Triphenylamine-Tether-Directed Synthesis of [60]Fullerene Bis-Adducts
- Source :
- ChemInform. 40
- Publication Year :
- 2009
- Publisher :
- Wiley, 2009.
-
Abstract
- The tether-directed regioselective synthesis of equatorial bis-adducts of [60]fullerene via the 1,3-dipolar cycloaddition reaction of azomethine ylides is reported. A mono-[60]fulleropyrrolidine adduct, derived via 1,3-dipolar cycloaddition of azomethine ylides generated in situ upon thermal condensation of triphenylamine bis-aldehyde and an α-amino acid, was isolated and further reacted to yield, exclusively and selectively, the equatorial bis-adduct, which is structurally characterized by appropriate spectroscopic means.
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........eec6d4fbaaa421dd41202b81922f7e9e