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A novel TiN coated CNTs nanocomposite CNTs@TiN supported Pt electrocatalyst with enhanced catalytic activity and durability for methanol oxidation reaction
- Source :
- International Journal of Hydrogen Energy. 42:12467-12476
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- The application of direct methanol fuel cells (DMFCs) is hampered by not only low activity but also poor stability and poor CO tolerance by the Pt catalyst. Herein, a novel titanium nitride coated multi-walled carbon nanotubes (CNTs@TiN) hybrid support was successfully synthesized by a facile solvothermal process followed by a nitriding process, and this hybrid support was used as Pt support for the oxidation of methanol. The structure, morphology and composition of the synthesized CNTs@TiN exhibits a uniform particle perfect coating with high purity and interpenetrating network structure. Notably, Pt/CNTs@TiN also showed excellent stability, experiencing only a slight performance loss after 5000 potential cycles. The onset potential (0.34 V) of CO oxidation on Pt/CNTs@TiN is obviously more negative than that on the Pt/TiN (0.38 V) and Pt/CNTs (0.48 V) in the first forward scan. In the Pt 4f XPS spectra, plentiful Pt atoms existed as Pt(II) in the Pt/CNTs and Pt/TiN catalysts, while a relatively smaller amount of Pt(II) was observed in the Pt/CNTs@TiN catalyst. The synthetic Pt/CNTs@TiN catalyst was studied with respect to its electrocatalytic activity and durability and CO tolerance toward methanol oxidation might be mainly attributed to the strongly coupled Pt–TiN and the fast electron-transport network structure. This work may provide more insight into developing novel catalyst supports of various transition metal nitrides coated CNTs for DMFCs with high activity and good durability and excellent CO tolerance.
- Subjects :
- Nanocomposite
Materials science
Renewable Energy, Sustainability and the Environment
Inorganic chemistry
Energy Engineering and Power Technology
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
Electrocatalyst
01 natural sciences
Titanium nitride
0104 chemical sciences
Catalysis
chemistry.chemical_compound
Fuel Technology
chemistry
Methanol
0210 nano-technology
Tin
Methanol fuel
Nitriding
Subjects
Details
- ISSN :
- 03603199
- Volume :
- 42
- Database :
- OpenAIRE
- Journal :
- International Journal of Hydrogen Energy
- Accession number :
- edsair.doi...........ef92a1aa1d5a58b5e612c838302c4973
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2017.03.181