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An Unexpected Domino Reaction of β-Keto Sulfones with Acetylene Ketones Promoted by Base: Facile Synthesis of 3(2H )-Furanones and Sulfonylbenzenes
- Source :
- Advanced Synthesis & Catalysis. 359:4025-4035
- Publication Year :
- 2017
- Publisher :
- Wiley, 2017.
-
Abstract
- An unexpected domino reaction of β-keto sulfones with acetylene ketones has been developed. The domino reaction of β-keto sulfones with diynones proceeded smoothly in the 30% mol K2CO3 without other additives, and afforded the novel 3(2H)-furanone derivatives. Replaced diynones with terminal alkyne ketones, the reaction regioselectivity was changed and sulfonylbenzenes were obtained via the benzannulation in good yields.
Details
- ISSN :
- 16154150
- Volume :
- 359
- Database :
- OpenAIRE
- Journal :
- Advanced Synthesis & Catalysis
- Accession number :
- edsair.doi...........efdccf08f36a1136e6b33f2520d0990f