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Thermodynamic Functions for Solubility of 1-Hydroxybenzotriazole in Sixteen Solvents at Temperatures from (278.15 to 313.15) K and Mixing Property of Mixtures

Authors :
Chao Cheng
Hongkun Zhao
Gaoquan Chen
Jiao Chen
Cunbin Du
Yang Cong
Source :
Journal of Chemical & Engineering Data. 62:2191-2197
Publication Year :
2017
Publisher :
American Chemical Society (ACS), 2017.

Abstract

Solubility of 1-hydroxybenzotriazole in 16 neat solvents including methanol, ethanol, n-propanol, isopropanol, acetone, butanone, isoamyl alcohol, n-hexanol, n-heptanol, isooctyl alcohol, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), ethyl acetate, acetonitrile, 1,4-dioxane, and toluene was measured using the method of isothermal saturation over a temperature range from (278.15 to 313.15) K under atmospheric pressure (101.1 kPa). The mole fraction solubility of 1-hydroxybenzotriazole in the selected solvents increased with an increase of temperature. They followed the order from high to low in studied neat solvents: DMF > DMSO > ethanol > n-propanol > isopropanol > methanol > butanone > acetone >1,4-dioxane > n-heptanol > n-hexanol > isoamyl alcohol > isooctyl alcohol > ethyl acetate > acetonitrile > toluene. The obtained solubility data of 1-hydroxybenzotriazole in the studied solvents were correlated with the λh equation, modified Apelblat equation, and NRTL and Wilson models. The largest valu...

Details

ISSN :
15205134 and 00219568
Volume :
62
Database :
OpenAIRE
Journal :
Journal of Chemical & Engineering Data
Accession number :
edsair.doi...........f0d79a68a0540f298f682740efa2904c
Full Text :
https://doi.org/10.1021/acs.jced.7b00316