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Thermodynamic Functions for Solubility of 1-Hydroxybenzotriazole in Sixteen Solvents at Temperatures from (278.15 to 313.15) K and Mixing Property of Mixtures
- Source :
- Journal of Chemical & Engineering Data. 62:2191-2197
- Publication Year :
- 2017
- Publisher :
- American Chemical Society (ACS), 2017.
-
Abstract
- Solubility of 1-hydroxybenzotriazole in 16 neat solvents including methanol, ethanol, n-propanol, isopropanol, acetone, butanone, isoamyl alcohol, n-hexanol, n-heptanol, isooctyl alcohol, N,N-dimethylformamide (DMF), dimethyl sulfoxide (DMSO), ethyl acetate, acetonitrile, 1,4-dioxane, and toluene was measured using the method of isothermal saturation over a temperature range from (278.15 to 313.15) K under atmospheric pressure (101.1 kPa). The mole fraction solubility of 1-hydroxybenzotriazole in the selected solvents increased with an increase of temperature. They followed the order from high to low in studied neat solvents: DMF > DMSO > ethanol > n-propanol > isopropanol > methanol > butanone > acetone >1,4-dioxane > n-heptanol > n-hexanol > isoamyl alcohol > isooctyl alcohol > ethyl acetate > acetonitrile > toluene. The obtained solubility data of 1-hydroxybenzotriazole in the studied solvents were correlated with the λh equation, modified Apelblat equation, and NRTL and Wilson models. The largest valu...
- Subjects :
- Ethanol
010405 organic chemistry
General Chemical Engineering
Inorganic chemistry
Butanone
Ethyl acetate
02 engineering and technology
General Chemistry
Isoamyl alcohol
01 natural sciences
0104 chemical sciences
chemistry.chemical_compound
020401 chemical engineering
chemistry
Non-random two-liquid model
Acetone
Methanol
0204 chemical engineering
Solubility
Subjects
Details
- ISSN :
- 15205134 and 00219568
- Volume :
- 62
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical & Engineering Data
- Accession number :
- edsair.doi...........f0d79a68a0540f298f682740efa2904c
- Full Text :
- https://doi.org/10.1021/acs.jced.7b00316