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ChemInform Abstract: Homoallylic Alcohols and Trichloroacetamides as Hydrogen Bond Donors for Directed Dihydroxylation
- Source :
- ChemInform. 33
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- The synthesis and directed dihydroxylation of a series of homoallylic alcohols and trichloroacetamides is described. Using the combination of OsO 4 and TMEDA, moderate to high levels of stereoselectivity were obtained, depending upon the structure of the substrate. Proof of the structure of two osmate esters was obtained through X-ray crystallography.
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 33
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........f1ba905c2984603d0892d53417d94de6