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Synthesis of Dibenzo[f,h]quinolines by Stepwise C–H Arylation of 2-Phenylpyridine and Reductive Cyclodehydrogenation
- Source :
- Synthesis.
- Publication Year :
- 2023
- Publisher :
- Georg Thieme Verlag KG, 2023.
-
Abstract
- A synthetic approach to dibenzo[f,h]quinolines and their derivatives via stepwise ruthenium-catalyzed C–H arylation and potassium-mediated reductive cyclodehydrogenation from 2-phenylpyridine and aryl bromides, is presented. One dibenzo[f,h]quinoline derivative is used as a bidentate ligand to prepare a cyclometalated ruthenium complex. Two dibenzo[f,h]quinoline compounds and the ruthenium complex were characterized by single-crystal X-ray structural analysis.
- Subjects :
- Organic Chemistry
Catalysis
Subjects
Details
- ISSN :
- 1437210X and 00397881
- Database :
- OpenAIRE
- Journal :
- Synthesis
- Accession number :
- edsair.doi...........f32a14272c2217b67b86d14abe6e86b4