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Amine-Induced Decomposition of Perfluoroalkanesulfonyl Fluorides

Authors :
Helmut Vorbrüggen
Ulrich Klar
B. Bennua‐Skalmowski
Source :
Synthesis. 2008:1175-1178
Publication Year :
2008
Publisher :
Georg Thieme Verlag KG, 2008.

Abstract

Perfluoroalkanesulfonyl fluorides (C n F 2n+1 SO 2 F) decompose slowly even at -20 °C in the presence of tertiary heteroaromatic or aliphatic amines to form the corresponding perfluorinated alkanes (C n F 2n+2 ) and amine-sulfur dioxide adducts.

Details

ISSN :
1437210X and 00397881
Volume :
2008
Database :
OpenAIRE
Journal :
Synthesis
Accession number :
edsair.doi...........f352d801c0e28062a44fdf3c2adc7069
Full Text :
https://doi.org/10.1055/s-2008-1067007