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IMPROVED SYNTHESIS OF DIALKYLTHIOXAPHOSPHORANESULFENYL CHLORIDES AND BROMIDES

Authors :
Leszek Łuczak
Jan Michalski
Andrzej Łopusiński
Source :
Phosphorous and Sulfur and the Related Elements. 40:233-236
Publication Year :
1988
Publisher :
Informa UK Limited, 1988.

Abstract

Dialkylthioxaphosphoranesulfenyl chlorides and bromides can be conveniently prepared in the reaction of the corresponding thioamides with hydrogen chloride generated in situ with trimethylsilyl chloride and ethanol. Stability of the chlorides and bromides obtained by this method is high and the yields are quantitative.

Subjects

Subjects :
chemistry.chemical_compound
Ethanol
Trimethylsilyl chloride
chemistry
Organic chemistry
Hydrogen chloride
Combinatorial chemistry

Details

ISSN :
0308664X
Volume :
40
Database :
OpenAIRE
Journal :
Phosphorous and Sulfur and the Related Elements
Accession number :
edsair.doi...........f37ab22ce8f87169e64a6b56449358b6
Full Text :
https://doi.org/10.1080/03086648808072919
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