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Delocalization-to-Localization Charge Transition in Divinylthiophene-Bridged Biruthenium Complexes as a Function of Length of the Bridging Chain by Both IR Spectroscopy and Theoretical Investigations
- Source :
- The Journal of Physical Chemistry C. 123:15425-15433
- Publication Year :
- 2019
- Publisher :
- American Chemical Society (ACS), 2019.
-
Abstract
- A series of biruthenium complexes linked by oligothiophene bridges of variable lengths (4a–4d) have been prepared to probe intramolecular electronic delocalization as a function of the chain length...
- Subjects :
- Materials science
Bridging (networking)
Infrared spectroscopy
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Delocalized electron
Crystallography
Chain length
General Energy
Intramolecular force
Physical and Theoretical Chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 19327455 and 19327447
- Volume :
- 123
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry C
- Accession number :
- edsair.doi...........f4cafbc8bfb5757b2eefb42b5db77f97
- Full Text :
- https://doi.org/10.1021/acs.jpcc.9b02478