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Synthesis and characterizations of a novel 2-D organic–inorganic hybrid constructed from mixed ligands and mixed-valence copper(I/II)
- Source :
- Inorganic Chemistry Communications. 13:262-265
- Publication Year :
- 2010
- Publisher :
- Elsevier BV, 2010.
-
Abstract
- A new 2-D inorganic–organic hybrid constructed from mixed-valence Cu(I/II) ions and mixed ligands, [ Cu 4 I Cu II ( sip ) 2 ( bipy ) 4 ( H 2 O ) 2 ] n (H3sip = 5-sulfoisophthalic acid, bipy = 4,4′-bipyridine), has been synthesized and characterized by IR, TGA, XPS, EPR and single-crystal X-ray diffraction. Two different kinds of chains in the compound constructed from [CuO4] planar squares and [CuN2O] triangulars, respectively, further interconnect together to give rise to an interesting 2-D layer framework. The compound exhibits strong yellow emission at 445 nm excited by 378 nm in the solid state at room temperature.
- Subjects :
- Photoluminescence
Valence (chemistry)
Materials science
Inorganic chemistry
chemistry.chemical_element
Crystal structure
Copper
law.invention
Inorganic Chemistry
Crystallography
chemistry
X-ray photoelectron spectroscopy
law
Excited state
Materials Chemistry
Hydrothermal synthesis
Physical and Theoretical Chemistry
Electron paramagnetic resonance
Subjects
Details
- ISSN :
- 13877003
- Volume :
- 13
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Communications
- Accession number :
- edsair.doi...........f600ef81de7496ecb0a68e7d308c0c03