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Synthesis, Crystal Structure, and Properties of the Novel 2D Cd Coordination Polymer Based on Cd4 Cluster Chains
- Source :
- Journal of Cluster Science. 29:1023-1029
- Publication Year :
- 2018
- Publisher :
- Springer Science and Business Media LLC, 2018.
-
Abstract
- The title complex Cd/4-(phosphonomethyl) benzoic acid 4-HOOCC6H14CH2PO3(H3BCP) with 1,10-phenanthroline has been hydrothermally synthesized directly as [Cd3(BCP)2(phen)]·H2O 1 (phen = 1,10-phenanthroline). The crystal structure was determined by single-crystal X-ray diffraction with the following data: triclinic P-1. The complex is a two-dimensional layer structure. Interestingly, the one-dimensional cluster chain is composed of the novel repeated La4 cluster units connected by two Cd3 ions. The adjacent cluster chains link to be 2D layer structure by the coordination interaction of oxygen atoms of the carboxyl with the Cd3 ions of the adjacent chains. It is worthy of mentioning that IR, photo-luminescent and solid UV–Vis spectrum are employed in order to explore the structural characteristics.
- Subjects :
- 010405 organic chemistry
Coordination polymer
Nanochemistry
General Chemistry
Crystal structure
Triclinic crystal system
010402 general chemistry
Condensed Matter Physics
01 natural sciences
Biochemistry
0104 chemical sciences
Catalysis
Ion
chemistry.chemical_compound
Crystallography
chemistry
Cluster (physics)
General Materials Science
Benzoic acid
Subjects
Details
- ISSN :
- 15728862 and 10407278
- Volume :
- 29
- Database :
- OpenAIRE
- Journal :
- Journal of Cluster Science
- Accession number :
- edsair.doi...........f63c409bf094e0d91b66b5e2f4d7c42c