(Invited) Diameter-Dependent Optical Absorption and Energy Transfer from Encapsulated Dye Molecules to Single Wall Carbon Nanotubes

The hollow core and well-defined diameters of single-walled carbon nanotubes (SWCNTs) allow for creation of unique one-dimensional hybrid structures by encapsulation of various molecules. For instance, we previously demonstrated that in this way dipolar dye molecules can be naturally aligned in an ideal head-to-tail arrangement to create assemblies with a giant total nonlinear optical response.[1] Here, we show that the optical properties of dye molecules encapsulated in SWCNTs can be strongly modulated by the SWCNT diameter, indicating very specific diameter-dependent stacking and interactions of the molecules. The filling is thoroughly characterized by optical absorption, resonant Raman, and two-dimensional infrared photoluminescence excitation (PLE) spectroscopy. Energy transfer probed by PLE spectroscopy shows the absorption spectrum of the dyes to be strongly diameter-dependent, and transient absorption spectroscopy, simultaneously probing the encapsulated dyes and the host SWCNTs, demonstrates sub-picosecond EET from encapsulated molecules to the host SWCNTs. The design of these functional hybrid systems, with tuneable dye absorption, EET depending on the SWCNT diameter and the ability to remove all metallic SWCNTs by subsequent separation, demonstrates potential for implementation in dedicated photo-conversion devices. [1] S. Cambré, J. Campo et al., Nature Nanotechnol. 10, 248 (2015).