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Effect of temperature on molecular interactions between tri(butyl)methylphosphonium methylsulfate and furfural
- Source :
- The Journal of Chemical Thermodynamics. 149:106150
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- In this work, the effect of temperature on the molecular interactions between tri(butyl)methylphosphonium methylsulfate ([P4441][CH3SO4]) and furfural were studied over the entire composition range, temperature ranging from (293.15 to 323.15) K and at pressure 0.1 MPa, using the measured density (ρ), ultrasonic sound velocities (u) and viscosity (η) data. The excess molar volumes (VE), partial molar volumes ( V ¯ 1 and V ¯ 2 ), excess partial molar volumes ( V 1 E ¯ and V 2 E ¯ ), deviation in isentropic compressibilities (Δκs) and the deviation in viscosities (Δη) were evaluated using these properties as a function of the concentration of IL. The Redlich-Kister polynomial was used to correlate the VE, Δκs and Δη data. The intermolecular interactions and structural effects are analysed on the basis of the measured and derived properties. Such knowledge about the intermolecular interactions which occur between ([P4441][CH3SO4]) with furfural is beneficial in the development of structure–property correlations as well as new predictive models.
- Subjects :
- Molecular interactions
Work (thermodynamics)
Isentropic process
Chemistry
Intermolecular force
Analytical chemistry
02 engineering and technology
010402 general chemistry
Furfural
01 natural sciences
Atomic and Molecular Physics, and Optics
0104 chemical sciences
Viscosity
chemistry.chemical_compound
020401 chemical engineering
General Materials Science
0204 chemical engineering
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 00219614
- Volume :
- 149
- Database :
- OpenAIRE
- Journal :
- The Journal of Chemical Thermodynamics
- Accession number :
- edsair.doi...........f80eb7edb53c1026b89d1616ef72efc0