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Nucleophilic ring opening of C2-symmetric aziridines. Synthetic equivalents for the β-cation of aspartic acid

Authors :
Hardip K. Dhaliwal
Carin Birgersson
David Tanner
Source :
Tetrahedron Letters. 31:1903-1906
Publication Year :
1990
Publisher :
Elsevier BV, 1990.

Abstract

The non-racemic C2-symmetric azirdines7 and8, easily available from (+)- and (-)-tartaric acid, respectively, undergo rapid nucleophilic attack to yield products formally derived from the β-cation ofL- orD-aspartic acid.

Details

ISSN :
00404039
Volume :
31
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........f819f0f41d0603d488e46d69fa82bbeb
Full Text :
https://doi.org/10.1016/s0040-4039(00)98816-6