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'Me3Al-TMSOSO2CF3' A new reagent for conversion of carbonyl to geminal dimethyl functionality: Regiospecific synthesis of alkylated A ring of arotinoids

Authors :
Choung U. Kim
Peter F. Misco
Bing Yu Luh
Muzammil M. Mansuri
Source :
Tetrahedron Letters. 35:3017-3020
Publication Year :
1994
Publisher :
Elsevier BV, 1994.

Abstract

Regiospecific synthesis of alkylated A ring of arotinoids has been achieved by using Me3Al-TMSOSO2CF3 as a key reagent for conversion of carbonyl to a geminal dimethyl functionality.

Details

ISSN :
00404039
Volume :
35
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........f9adf47354d1ed11edaa71eede33707e
Full Text :
https://doi.org/10.1016/s0040-4039(00)76816-x