Back to Search
Start Over
Novel plasmon resonances of nonstoichiometric alumina
- Source :
- Applied Surface Science. 488:648-655
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Aluminum monoxide (AlO) and a nonstoichiometric alumina (n-alumina) with its chemical composition similar to that of AlO were proposed theoretically for a promising low-loss plasmonic material. However, they were rarely studied due to the high thermodynamic instability. Recently, n-aluminas with their O/Al atomic ratios close to 1 were found to form on Al nanospheres synthesized by electrical explosion. Although a new bulk plasmon resonance was observed below the excitonic transition energy from the n-aluminas, no investigation into surface plasmon resonance – the key component for plasmonics - was conducted yet. Here I report on surface plasmons of the n-aluminas discovered by spatially-resolved electron energy loss spectroscopy. Energy loss spectra collected from local spots of the n-aluminas are analyzed to reveal that there are two types of n-aluminas; one with two surface plasmons (n-alumina A) and the other with one surface plasmon (n-alumina B). Remarkably, the oscillator strengths of the novel surface plasmons are as high as that of surface plasmon of Al. The electronic band structure proposed for the n-alumina A shows a lossless energy zone. Consequently, current study demonstrates that the n-aluminas have the potential as a new low-loss plasmonic material.
- Subjects :
- Materials science
Physics::Medical Physics
Physics::Optics
General Physics and Astronomy
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
01 natural sciences
Molecular physics
Spectral line
Aluminium
Physics::Atomic and Molecular Clusters
Surface plasmon resonance
Electronic band structure
Plasmon
Electron energy loss spectroscopy
Surface plasmon
Monoxide
Surfaces and Interfaces
General Chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
0104 chemical sciences
Surfaces, Coatings and Films
chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 01694332
- Volume :
- 488
- Database :
- OpenAIRE
- Journal :
- Applied Surface Science
- Accession number :
- edsair.doi...........fa2d032464129ed56afd3d791c451ee7