Development of a Population Balance Model to Describe the Influence of Shear and Nanoparticles on the Aggregation and Fragmentation of Asphaltene Aggregates

The precipitation and deposition of asphaltenes is a primary problem related to the processing, transportation, and production of oil. Flocculation of asphaltene aggregates is likely to occur during the production and processing of crude oil. Recently, it has been shown that nanotechnology in the form of nanoparticles is useful for the inhibition or prevention of asphaltene formation damage. Although it is well-known that the adsorption of asphaltenes on the nanoparticle surface would reduce the capacity of these asphaltic compounds to interact with each other, limited studies have been performed regarding the processes and the mechanisms associated with the effect of nanoparticles on the inhibition of the formation damage due to asphaltenes. To better understand this phenomenon from a mathematical approach, a population balance model (PBM) is proposed to describe the kinetics of asphaltene flocculation-fragmentation in the presence of nanoparticles. The model assumes that asphaltenes in the presence of a...