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An Improved Synthesis of (-)-Martinellic Acid via Radical Addition-Cyclization-Elimination Reaction of Chiral Oxime Ether
- Source :
- Synlett. 2006:893-896
- Publication Year :
- 2006
- Publisher :
- Georg Thieme Verlag KG, 2006.
-
Abstract
- A concise formal synthesis of (-)-martinellic acid has been accomplished by preparing optically active dipyrroloquinoline as a key synthetic intermediate, which was prepared via the radical addition-cyclization-elimination of oxime ether carrying an unsaturated ester followed by two chemoselective reductions of the carbonyl groups.
Details
- ISSN :
- 14372096 and 09365214
- Volume :
- 2006
- Database :
- OpenAIRE
- Journal :
- Synlett
- Accession number :
- edsair.doi...........fb2dc487120f84c31c0ca87d49d9d4af