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Thermodynamic modeling of several alcohol-hydrocarbon binary mixtures at low to moderate conditions
- Source :
- Journal of Molecular Liquids. 346:117924
- Publication Year :
- 2022
- Publisher :
- Elsevier BV, 2022.
-
Abstract
- This study aims to precisely model vapor phase concentration and bubble pressure in correlating alcohol-hydrocarbon mixtures to accurate assessment with effects from literature by employed Patel-Teja equation of state and together with Wong-Sandler mixing rules. Even though other intricate equations have been used for some selected systems, it is the first time that a systematic approach for measuring hydrocarbon-alcohol mixtures in the range of low to moderate pressures has been practiced by this research. Results show that models employed in this work, average-absolute deviations are fewer than the previous EoSs for alcohol-hydrocarbons binary mixtures. The complex models calculate bubble pressure and vapor phase concentration respectively with 2.25% and 3.25% of average-absolute deviations, whiles our models show a better result for them (respectively, 0.00 % and 0.47% averagely).
- Subjects :
- chemistry.chemical_classification
Maximum bubble pressure method
Work (thermodynamics)
Equation of state
Materials science
Binary number
Thermodynamics
Alcohol
Condensed Matter Physics
Atomic and Molecular Physics, and Optics
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Hydrocarbon
chemistry
Materials Chemistry
Range (statistics)
Physical and Theoretical Chemistry
Spectroscopy
Mixing (physics)
Subjects
Details
- ISSN :
- 01677322
- Volume :
- 346
- Database :
- OpenAIRE
- Journal :
- Journal of Molecular Liquids
- Accession number :
- edsair.doi...........fca31c40e0ed4962d694a9dd7e14b5e8
- Full Text :
- https://doi.org/10.1016/j.molliq.2021.117924