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Thermodynamic modeling of several alcohol-hydrocarbon binary mixtures at low to moderate conditions

Authors :
Siamak Hoseinzadeh
Ali Sohani
Mona Zamani Pedram
Gowhar Ahmad Naikoo
Hiresh Moradi
Mohammad Bagher Asgharnejad Lamraski
Source :
Journal of Molecular Liquids. 346:117924
Publication Year :
2022
Publisher :
Elsevier BV, 2022.

Abstract

This study aims to precisely model vapor phase concentration and bubble pressure in correlating alcohol-hydrocarbon mixtures to accurate assessment with effects from literature by employed Patel-Teja equation of state and together with Wong-Sandler mixing rules. Even though other intricate equations have been used for some selected systems, it is the first time that a systematic approach for measuring hydrocarbon-alcohol mixtures in the range of low to moderate pressures has been practiced by this research. Results show that models employed in this work, average-absolute deviations are fewer than the previous EoSs for alcohol-hydrocarbons binary mixtures. The complex models calculate bubble pressure and vapor phase concentration respectively with 2.25% and 3.25% of average-absolute deviations, whiles our models show a better result for them (respectively, 0.00 % and 0.47% averagely).

Details

ISSN :
01677322
Volume :
346
Database :
OpenAIRE
Journal :
Journal of Molecular Liquids
Accession number :
edsair.doi...........fca31c40e0ed4962d694a9dd7e14b5e8
Full Text :
https://doi.org/10.1016/j.molliq.2021.117924