[Untitled]

Authors :: Marisol C. Ortega
Alvaro J. Pardey
Sergio A. Moya
E. Lujano
M. Fernández
Pablo J. Baricelli
Clementina Longo
Angel B. Rivas
José Brito
Source :: Reaction Kinetics and Catalysis Letters. 74:111-118
Publication Year :: 2001
Publisher :: Springer Science and Business Media LLC, 2001.
Abstract: Reported here is the influence of the reaction conditions variation (1-hexene/rhodium content (S/C) = 16 - 105, temperature (T) = 70 - 110 °C and carbon monoxide pressure (P(CO)) = 0.6 - 1.8 atm) on the catalytic hydroformylation of 1-hexene to aldehydes (heptanal and 2-methyl-hexanal) by the rhodium(I) complex, [Rh(COD)(2-picoline)2]PF6 (COD = 1,5-cyclooctadiene)immobilized on poly(4-vinylpyridine) in contact with 10 mL of 80% aqueous 2-ethoxyethanol, under water gas shift reaction condition.