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Advancement in Catalytic Asymmetric Hydrogenation of Ketones and Imines, and Development of Asymmetric Isomerization of Allylic Alcohols
- Source :
- The Chemical Record. 16:2801-2819
- Publication Year :
- 2016
- Publisher :
- Wiley, 2016.
-
Abstract
- Catalytic asymmetric hydrogenation of ketones through the "metal-ligand cooperative mechanism" has been improved in terms of the efficiency, stereoselectivity, and scope of substrates by varying the arrangement of the catalyst structure and reaction conditions. Imino compounds are also smoothly converted to the optically active amines with appropriate catalysts. This type of catalyst exhibits excellent performance on the asymmetric isomerization of primary allylic alcohols into the optically active aldehydes. This personal account describes recent progress on these topics.
- Subjects :
- Allylic rearrangement
genetic structures
General Chemical Engineering
Noyori asymmetric hydrogenation
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Biochemistry
isomerization
Catalysis
Materials Chemistry
Organic chemistry
heterocyclic compounds
ruthenium
010405 organic chemistry
organic chemicals
Asymmetric hydrogenation
Enantioselective synthesis
asymmetric catalysis
General Chemistry
iridium
0104 chemical sciences
Ruthenium
chemistry
Stereoselectivity
hydrogenation
Isomerization
Subjects
Details
- ISSN :
- 15278999
- Volume :
- 16
- Database :
- OpenAIRE
- Journal :
- The Chemical Record
- Accession number :
- edsair.doi.dedup.....002ac06f8954a0fc0d90eda542c0e271