Polymerization of ε-Caprolactone Initiated by Nd(BH4)3(THF)3: Synthesis of Hydroxytelechelic Poly(ε-caprolactone)

Authors :: Alain Soum
Michèle Schappacher
Sophie M. Guillaume
Laboratoire de Chimie des Polymères Organiques (LCPO)
Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC)
Source :: Macromolecules, Macromolecules, American Chemical Society, 2003, 36 (1), pp.54-60. ⟨10.1021/ma020993g⟩
Publication Year :: 2002
Publisher :: American Chemical Society (ACS), 2002.
Abstract: The ring-opening polymerization of e-caprolactone initiated by Nd(BH4)3(THF)3, 1a, has been investigated. The polymerization occurs rapidly (

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