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Near-IR-Triggered, Remote-Controlled Release of Metal Ions: A Novel Strategy for Caged Ions
- Source :
- Angewandte Chemie. 126:10854-10857
- Publication Year :
- 2014
- Publisher :
- Wiley, 2014.
-
Abstract
- A ligand incorporating a dithioethenyl moiety is cleaved into fragments which have a lower metal-ion affinity upon irradiation with low-energy red/near-IR light. The cleavage is a result of singlet oxygen generation which occurs on excitation of the photosensitizer modules. The method has many tunable factors that could make it a satisfactory caging strategy for metal ions.
- Subjects :
- Physics::Atomic and Molecular Clusters
General Medicine
Subjects
Details
- ISSN :
- 00448249
- Volume :
- 126
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie
- Accession number :
- edsair.doi.dedup.....005dcdaf3fa19c569f23ec2f1a7d939d