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Exploration of the reaction of potassium organotrifluoroborates with porphyrins
- Source :
- Tetrahedron Letters. 50:2562-2565
- Publication Year :
- 2009
- Publisher :
- Elsevier BV, 2009.
-
Abstract
- PUBLISHED<br />A general method that uses potassium organotrifluoroborates in the Suzuki?Miyaura cross-coupling reaction with ring-brominated porphyrins has been investigated. The reaction conditions tolerate various functional groups and are applicable to the meso- and ?-position as well as to aryl- and alkyl-substituted porphyrins. Depending on the nature of the potassium organotrifluoroborate, the coupling products can be obtained in yields of up to 75%.<br />Science Foundation Ireland Research Professorship grant (SFI/04/RP1/B482)
- Subjects :
- Reaction conditions
General method
Potassium
Aryl
Organic Chemistry
chemistry.chemical_element
Biochemistry
Porphyrin
Chemistry
chemistry.chemical_compound
chemistry
Suzuki reaction
Organotrifluoroborate
Drug Discovery
Organic chemistry
GeneralLiterature_REFERENCE(e.g.,dictionaries,encyclopedias,glossaries)
Subjects
Details
- ISSN :
- 00404039
- Volume :
- 50
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi.dedup.....007d128a804bcd3d7efff79ab6420a19
- Full Text :
- https://doi.org/10.1016/j.tetlet.2009.03.098