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{Mn14W48} aggregate: the perspective of isopolyanions as ligands

Authors :
Xikui Fang
Marshall Luban
Source :
Chemical Communications. 47:3066
Publication Year :
2011
Publisher :
Royal Society of Chemistry (RSC), 2011.

Abstract

The assembly of a tetradeca-manganese magnetic cluster [Mn(14)W(48)O(192)H(20)](26-), containing two high spin Mn(7) cores and supported exclusively by isopolytungstate ligands, demonstrates the promising perspective of using "defect" isopolyanions as ligands/synthons to construct large aggregated structures and model the surface deposition of molecular magnets.

Subjects

Subjects :
Materials science
Molecular magnets
Stereochemistry
Synthon
Aggregate (data warehouse)
Metals and Alloys
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Crystallography
Materials Chemistry
Ceramics and Composites
Cluster (physics)

Details

ISSN :
1364548X and 13597345
Volume :
47
Database :
OpenAIRE
Journal :
Chemical Communications
Accession number :
edsair.doi.dedup.....07d05c914d66b528744a10ee7f64ba9a
Full Text :
https://doi.org/10.1039/c0cc04403b
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