Solution Processable Benzotrithiophene (BTT)‐Based Organic Semiconductors: Recent Advances and Review

Conjugated polymers and small molecules (SMs) with fused electron-rich and electron-deficient building blocks are promising materials for low-cost organic electronic devices. Benzotrithiophene (BTT) is one such electron-rich hybrid building block composed of three fused thiophene moieties with an extended π-system that has been widely used to synthesize a variety of electronic materials. Additionally, BTT has a planar and sulfur-rich core with a number of distinct advantages, including structural diversity, tunable electro-optical properties and exceptional hole-transport behavior. So far, four BTT-based isomers have been synthesized on a gram scale from seven isomeric structures, three of which are symmetric (BTT1-3) and one of which is asymmetric (BTT5), for use in a variety of optoelectronic applications. However, no report summarizing the progress of BTT-based semiconductors for electronic applications is available. The current review presents an overview of the recent developments in BTT-based monomers, polymers and SMs, as well as their applications in energy harvesting. Additionally, recent advances on charge transport devices, most notably organic solar cells (OSCs), organic thin field-effect transistors (OTFTs), and perovskite solar cells (Pero-SCs) are also surveyed and summarized. It is anticipated that this comprehensive review will stimulate further research and development of future BTT-based electronic materials, particularly for low-cost and high-performance organic electronic devices.