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cis-(Benzenethiolato)bis(tert-butyl isocyanide)carbonyl(cyclopentadienyl)molybdenum(II), [Mo(C6H5S)(C5H9N)2(C5H5)(CO)]
- Source :
- Acta Crystallographica Section C Crystal Structure Communications, Acta Crystallographica Section C Crystal Structure Communications, 1996, 52 (1), pp.74-77. ⟨10.1107/S0108270195009486⟩
- Publication Year :
- 1996
- Publisher :
- International Union of Crystallography (IUCr), 1996.
-
Abstract
- International audience; In [CpMo(SPh)(CO)(CNtBu)2], Cp = η5-C5H5, the Mo atom adopts conventional four-legged piano-stool coordination geometry; a pair of cis CNtBu ligands, together with carbonyl and benzenethiolato groups, make up the base. The Mo-CNtBu bond lengths [2.053 (4) Å trans to S, 2.086 (4) Å trans to CO] show a small but significant difference.
- Subjects :
- chemistry.chemical_classification
Base (chemistry)
Stereochemistry
Significant difference
chemistry.chemical_element
General Medicine
Crystal structure
010402 general chemistry
010403 inorganic & nuclear chemistry
01 natural sciences
Medicinal chemistry
General Biochemistry, Genetics and Molecular Biology
0104 chemical sciences
3. Good health
Bond length
chemistry.chemical_compound
Cyclopentadienyl complex
chemistry
Molybdenum
[CHIM]Chemical Sciences
Molecule
tert-Butyl isocyanide
Subjects
Details
- ISSN :
- 01082701
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section C Crystal Structure Communications
- Accession number :
- edsair.doi.dedup.....0d0ace1a48ca28bc1a494f3bb72ca8c6
- Full Text :
- https://doi.org/10.1107/s0108270195009486