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A switchable dual organocatalytic system and the enantioselective total synthesis of the quadrane sesquiterpene suberosanone
- Source :
- Chemical Communications, Chemical Communications, 2016, 52 (39), pp.6565-6568. ⟨10.1039/c6cc01689h⟩, Chemical Communications, Royal Society of Chemistry, 2016, 52 (39), pp.6565-6568. ⟨10.1039/c6cc01689h⟩
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- International audience; The combination of aminocatalysis with N-heterocyclic carbene catalysis has been extended to a switchable dual catalytic system, which allowed a direct enantioselective entry to bridged bicyclo[3.n.1] ring systems and the total synthesis of the natural product (1R)-suberosanone.
- Subjects :
- Stereochemistry
Chemistry Techniques, Synthetic
010402 general chemistry
Ring (chemistry)
01 natural sciences
Catalysis
chemistry.chemical_compound
multicatalysis
Materials Chemistry
total synthesis
enantioselective catalysis
Natural product
Bicyclic molecule
[CHIM.ORGA]Chemical Sciences/Organic chemistry
010405 organic chemistry
Circular Dichroism
Metals and Alloys
Absolute configuration
Enantioselective synthesis
Total synthesis
Stereoisomerism
[CHIM.CATA]Chemical Sciences/Catalysis
General Chemistry
reactivity switch
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
absolute configuration
Optical Rotatory Dispersion
chemistry
Ceramics and Composites
Sesquiterpenes
Carbene
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 52
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi.dedup.....0d69be01022b67f01b988de3e9839da0
- Full Text :
- https://doi.org/10.1039/c6cc01689h