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Ruthenium complexes bearing amino-bis(phosphinite) or amino-bis(aminophosphine) ligands: Application in catalytic ester hydrogenation
- Source :
- Molecular Catalysis, Molecular Catalysis, Elsevier, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩, Molecular Catalysis, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩
- Publication Year :
- 2017
- Publisher :
- HAL CCSD, 2017.
-
Abstract
- International audience; Mononuclear hydrido and dinuclear chloro ruthenium(II) complexes derived from readily available amino-bis(phosphinite) and amino(bisaminophosphine) tridentate ligands were applied in the catalytic hydrogenation of ester derivatives. Notably, the cationic ruthenium dimer 2c proved to be an efficient pre-catalyst when used in combination with (KOBu)-Bu-t in THF at 120 degrees C and 50 bar H-2 with aromatic and aliphatic esters. (C) 2017 Elsevier B.V. All rights reserved.
- Subjects :
- inorganic chemicals
Phosphinite
Dimer
chemistry.chemical_element
Noyori asymmetric hydrogenation
Homogeneous catalysis
010402 general chemistry
01 natural sciences
Medicinal chemistry
Catalysis
chemistry.chemical_compound
ester hydrogenation
Organic chemistry
[CHIM]Chemical Sciences
Physical and Theoretical Chemistry
ruthenium
Ester derivatives
010405 organic chemistry
Process Chemistry and Technology
Cationic polymerization
homogeneous catalysis
0104 chemical sciences
Ruthenium
chemistry
pincer complexes
Subjects
Details
- Language :
- English
- ISSN :
- 24688231
- Database :
- OpenAIRE
- Journal :
- Molecular Catalysis, Molecular Catalysis, Elsevier, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩, Molecular Catalysis, 2017, 432, pp.15--22. ⟨10.1016/j.mcat.2017.01.025⟩
- Accession number :
- edsair.doi.dedup.....0d98296bae0e3e513283d242f208a2fc
- Full Text :
- https://doi.org/10.1016/j.mcat.2017.01.025⟩