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Novel quenchometric oxygen sensing material based on diiodine-substituted boron dipyrromethene dye

Authors :
Yu. V. Aksenova
Elena V. Antina
Ruslan M. Gadirov
Alexander S. Semeikin
Rimma T Kuznetsova
Mikhail B. Berezin
E. G. Ermolina
T. N. Kopylova
Томский государственный университет Сибирский физико-технический институт Научные подразделения СФТИ
Томский государственный университет Физический факультет Научные подразделения ФФ
Source :
Sensors and actuators B : Chemical. 2014. Vol. 197. P. 206-210
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

Emission spectra of diiodine-substituted boron dipyrromethene (I2BODIPY) dye in ethanol solutions and in methylcellulose matrix were studied. The solid patterns were photoexcited at 520 nm and display room temperature phosphorescence with a maximum at 790 nm that is quenched by molecular oxygen at room temperature. Novel sensing material for oxygen concentration detection from 0% to 100% has been developed on the basis of I2BODIPY with 17-fold sensitivity (IAr/IO2), reverse, fast response (1 s) and linear calibration. The sensitivity dependence on the active substance concentration in matrix was shown.

Details

ISSN :
09254005
Volume :
197
Database :
OpenAIRE
Journal :
Sensors and Actuators B: Chemical
Accession number :
edsair.doi.dedup.....0df05406939f57c1f29c4e06698bf8c3
Full Text :
https://doi.org/10.1016/j.snb.2014.02.085