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Influence of the support of copper catalysts on activity and 1,2-dichloroethane selectivity in ethylene oxychlorination
- Source :
- Applied Catalysis A: General. 556:41-51
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- Five different support materials were modified with 5 wt.% Cu, using an evaporation impregnation method. The synthesized CuCl 2 /γ-Al 2 O 3 , CuCl 2 /TiO 2 (Hombikat), CuCl 2 /TiO 2 (Alfa Aesar), CuCl 2 /SiO 2 and CuCl 2 /H-Beta-25 materials were characterized by nitrogen physisorption, X-ray powder diffraction, scanning electron microscopy, energy dispersive Xray microanalysis, transmission electron microscopy, Fourier transform infrared spectroscopy and CO 2 -temperature programmed desorption. The physical-chemical characterization was correlated with catalytic activity, stability and selectivity in the ethylene oxychlorination. It was found that γ-Al 2 O 3 and TiO 2 support materials demonstrate very good activity and 1,2dichloroethane selectivity compare to other catalysts. Zeolite H-Beta-25 and SiO 2 support materials proved to be unusable for this reaction.
- Subjects :
- Thermal desorption spectroscopy
Process Chemistry and Technology
Oxychlorination
02 engineering and technology
1,2-Dichloroethane
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Catalysis
0104 chemical sciences
chemistry.chemical_compound
chemistry
Physisorption
Fourier transform infrared spectroscopy
0210 nano-technology
Zeolite
Selectivity
ta116
Nuclear chemistry
Subjects
Details
- ISSN :
- 0926860X
- Volume :
- 556
- Database :
- OpenAIRE
- Journal :
- Applied Catalysis A: General
- Accession number :
- edsair.doi.dedup.....0e4b350fe07ead0b89b7c65eb65c8e52
- Full Text :
- https://doi.org/10.1016/j.apcata.2018.02.012