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Di-μ-perchlorato-bis{μ-2-[(2-pyridyl)methylaminomethyl]phenolato)dicopper(II) acetonitrile disolvate

Authors :
Yilma Gultneh
Teshome B. Yisgedu
Ray J. Butcher
Gervas E. Assey
Yohannes T. Tesema
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2009
Publisher :
International Union of Crystallography (IUCr), 2009.

Abstract

In the crystal of the dinuclear title compound, [Cu(2)(C(13)H(13)N(2)O)(2)(ClO(4))(2)]·2CH(3)CN, the two bridging perchlorate ions chelate to the two Cu(II) atoms in a μ-O:O' fashion on opposite sides of the equatorial plane. The Cu(II) ions display a distorted octa-hedral coordination geometry (in the usual 4 + 2 Jahn-Teller arrangement), each being coordinated by two O atoms from the two perchlorate ligands, and two N and O atoms from the reduced Schiff base ligand. The asymmetric unit contains two acetonitrile solvent mol-ecules. In the crystal structure, in addition to N-H⋯O hydrogen bonds, there are weak C-H⋯O inter-actions between the perchlorate O atoms and the reduced Schiff base ligand. C-H⋯N inter-actions are also present.

Details

ISSN :
16005368
Volume :
65
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi.dedup.....0ef3a91db53901b66b47970c277b7cac
Full Text :
https://doi.org/10.1107/s1600536809029134