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Bis[2-(2-hy-droxy-meth-yl)pyridine-κ(2)N,O](pivalato-κO)copper(II)

Authors :
Priti Ram
Anil Birla
Veenu Mishra
Mobin M. Shaikh
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2012

Abstract

The structure of the centrosymmetric title complex, [Cu(C5H9O2)2(C6H7NO)2], has the CuIIatom on a centre of inversion. The CuIIatom is six-coordinate with a distorted octahedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxylate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by intermolecular C—H...O and intramolecular O—H...O hydrogen-bond interactions.

Details

ISSN :
16005368
Volume :
68
Issue :
Pt 8
Database :
OpenAIRE
Journal :
Acta crystallographica. Section E, Structure reports online
Accession number :
edsair.doi.dedup.....14407fa7d08c474091bd0f2bbd1f4758