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Rhodium-Catalyzed Direct Addition of Aryl C–H Bonds to Nitrosobenzenes at Room Temperature
- Source :
- Organic Letters. 15:6302-6305
- Publication Year :
- 2013
- Publisher :
- American Chemical Society (ACS), 2013.
-
Abstract
- An unprecedented Rh-catalyzed direct addition of aryl C-H bonds to nitrosobenzenes has been developed under very mild reaction conditions (room temperature). The reaction is highly step-, atom-, and redox-economic and compatible with air and water to N-selectively provide a variety of N-diarylhydroxylamines in good to excellent yields. More importantly, this process may provide a new direction for C-N bond formation through direct C(sp(2))-H functionalization.
- Subjects :
- Models, Molecular
Reaction conditions
Molecular Structure
Chemistry
Aryl
Organic Chemistry
Temperature
chemistry.chemical_element
Bond formation
Crystallography, X-Ray
Hydroxylamines
Photochemistry
Biochemistry
Catalysis
Rhodium
chemistry.chemical_compound
Atom
Organometallic Compounds
Surface modification
Physical and Theoretical Chemistry
Nitroso Compounds
Subjects
Details
- ISSN :
- 15237052 and 15237060
- Volume :
- 15
- Database :
- OpenAIRE
- Journal :
- Organic Letters
- Accession number :
- edsair.doi.dedup.....1472aa03b00f995c10d1366b7fda3d60