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A homochiral Zn-Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration
- Source :
- Chemical communications (Cambridge, England). 54(95)
- Publication Year :
- 2018
-
Abstract
- Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn–Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of perchlorate anions.
- Subjects :
- Left handed
Materials science
010405 organic chemistry
Metals and Alloys
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
Helical chain
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ion
Nonlinear optical
Crystallography
Perchlorate
chemistry.chemical_compound
chemistry
Materials Chemistry
Ceramics and Composites
Cluster (physics)
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 54
- Issue :
- 95
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....150cf62a9df44e70cceee840ee417c7e