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Extending the corrole ring conjugation: preparation of β,β′-fused 2,3-[1′,2′-b]pyrazinocorroles
- Source :
- Organic & Biomolecular Chemistry. 14:2891-2897
- Publication Year :
- 2016
- Publisher :
- Royal Society of Chemistry (RSC), 2016.
-
Abstract
- A novel method for the preparation of corroles with β-fused pyrazino rings was developed, exploiting a one-pot reaction of 2,3-diaminocorroles (or 2,3,17,18-tetraaminocorroles) with different diones; a variety of π-extended corroles were obtained in moderate yields as copper complexes, which can then be demetallated to give the corresponding free base in good yields.
- Subjects :
- 010405 organic chemistry
Chemistry
Stereochemistry
Settore CHIM/07 - Fondamenti Chimici delle Tecnologie
Organic Chemistry
Free base
chemistry.chemical_element
010402 general chemistry
Ring (chemistry)
01 natural sciences
Biochemistry
Combinatorial chemistry
Copper
0104 chemical sciences
chemistry.chemical_compound
Physical and Theoretical Chemistry
Corrole
Subjects
Details
- ISSN :
- 14770539 and 14770520
- Volume :
- 14
- Database :
- OpenAIRE
- Journal :
- Organic & Biomolecular Chemistry
- Accession number :
- edsair.doi.dedup.....1767979ab3136b79d8cb2bd45eaca9cb