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Synthesis of a New Stable Conformationally Constrained 2,7-Anhydrosialic Acid Derivative
Synthesis of a New Stable Conformationally Constrained 2,7-Anhydrosialic Acid Derivative
- Source :
- The Journal of Organic Chemistry. 68:9528-9531
- Publication Year :
- 2003
- Publisher :
- American Chemical Society (ACS), 2003.
-
Abstract
- A stereoseletive synthesis of 2,7-anhydrosialic acid derivative 18 was achieved from d-glucono-delta-lactone. A highly syn-selective addition of Grignard reagent to theN-benzylimine 8 served as a key step.
- Subjects :
- chemistry.chemical_classification
Molecular Structure
Stereochemistry
Organic Chemistry
Imine
Molecular Conformation
Stereoisomerism
Gluconates
Chemical synthesis
N-Acetylneuraminic Acid
Lactones
chemistry.chemical_compound
Models, Chemical
chemistry
Aldonic acid
Stereoselectivity
Selectivity
N-Acetylneuraminic acid
Lactone
Subjects
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 68
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi.dedup.....1816e8569ab865862ef3002f5462868f
- Full Text :
- https://doi.org/10.1021/jo034679b