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Synthesis of a New Stable Conformationally Constrained 2,7-Anhydrosialic Acid Derivative

Synthesis of a New Stable Conformationally Constrained 2,7-Anhydrosialic Acid Derivative

Authors :
Haibin Zhou
Yu-Lin Wu
Zhu-Jun Yao
Kegang Liu
Source :
The Journal of Organic Chemistry. 68:9528-9531
Publication Year :
2003
Publisher :
American Chemical Society (ACS), 2003.

Abstract

A stereoseletive synthesis of 2,7-anhydrosialic acid derivative 18 was achieved from d-glucono-delta-lactone. A highly syn-selective addition of Grignard reagent to theN-benzylimine 8 served as a key step.

Details

ISSN :
15206904 and 00223263
Volume :
68
Database :
OpenAIRE
Journal :
The Journal of Organic Chemistry
Accession number :
edsair.doi.dedup.....1816e8569ab865862ef3002f5462868f
Full Text :
https://doi.org/10.1021/jo034679b