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A solid state highly emissive Cu(i) metallacycle: promotion of cuprophilic interactions at the excited states
- Source :
- Chemical Communications, Chemical Communications, Royal Society of Chemistry, 2016, 52 (76), pp.11370-11373. ⟨10.1039/C6CC06613E⟩, Chemical Communications, 2016, 52 (76), pp.11370-11373. ⟨10.1039/C6CC06613E⟩
- Publication Year :
- 2016
-
Abstract
- The straightforward synthesis of a new Cu(I) metal-rich small metallacycle is presented. This compound is luminescent in the solid state with an emission quantum yield of 72% at room temperature and displays a pronounced reversible red-shift of its emission spectra upon cooling. Quantum chemical calculations reveal that these properties are governed by important geometrical relaxations that imply the formation of cuprophilic interactions at the excited states.
- Subjects :
- Quantum chemical
010405 organic chemistry
Chemistry
Metals and Alloys
Solid-state
Quantum yield
General Chemistry
Metallacycle
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
010402 general chemistry
Photochemistry
01 natural sciences
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Excited state
Materials Chemistry
Ceramics and Composites
Emission spectrum
Luminescence
ComputingMilieux_MISCELLANEOUS
Subjects
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 52
- Issue :
- 76
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....182ba58565a2a9aea8795e3227ea8353
- Full Text :
- https://doi.org/10.1039/C6CC06613E⟩