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Sequence-specific self-sorting of the binding sites of a ditopic guest by cucurbituril homologues and subsequent formation of a hetero[4]pseudorotaxane
- Source :
- Chemistry-A European Journal, Chemistry : A European Journal, 15(40), 10360-10363. Wiley-VCH Verlag
- Publication Year :
- 2009
-
Abstract
- Ties us together: The selectivity and recognition behavior of cucurbit[n]uril (CB[n]) homologues (n = 6,7,8) towards a ditopic guest containing two distinct binding sites is explored. CB6, CB7, and CB8 recognize and self-sort the binding sites according to their size, shape, and chemical nature. In the presence of both CB6 and CB8 a hetero[4]pseudorotaxane is formed. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
- Subjects :
- Macrocyclic Compounds
Rotaxanes
Stereochemistry
Binding sites
Supramolecular chemistry
Sequence (biology)
Self recognition
Binding energy
Catalysis
Ditopic guests
Mass Spectrometry
Selfsorting
Synthesis
Chemical structure
Cucurbituril
Chemical nature
Binding site
Binding Sites
Mass spectrometry
Molecular Structure
Chemistry
Organic Chemistry
General Chemistry
Self-recognition
Self sorting
Macromolecules
Macrocyclic compounds
Recognition behavior
Selectivity
Molecular structure
Subjects
Details
- ISSN :
- 15213765 and 09476539
- Volume :
- 15
- Issue :
- 40
- Database :
- OpenAIRE
- Journal :
- Chemistry (Weinheim an der Bergstrasse, Germany)
- Accession number :
- edsair.doi.dedup.....1f1ee044fc761f7271e7b8d52e1b71a1