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Adsorption and corrosion of renewable inhibitor of Pomelo peel extract for mild steel in phosphoric acid solution
- Source :
- Arabian Journal of Chemistry, Vol 14, Iss 5, Pp 103114-(2021)
- Publication Year :
- 2021
- Publisher :
- Elsevier, 2021.
-
Abstract
- Pomelo peel extract (PPE) was evaluated as green and renewable corrosion inhibitor for mild steel in 1.0 mol/L H3PO4 solution. The inhibition behaviour was studied using mass loss, potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) measurements. The chemical structure of PPE was investigated using Fourier transform infrared (FT-IR) and ultraviolet-visible (UV–vis) spectroscopy. The corrosion morphology of mild steel was analysed via scanning electron microscopy (SEM). The adsorption thermodynamics and kinetics was discussed. The results show that PPE confers an acceptable long-term effect (inhibition efficiency of 95.0% and 92.8% for corroding 23 h and 224 h in the presence of 5.0 g/L PPE inhibitor) and functions as a mixed inhibitor. The adsorption of PPE on mild steel simultaneously follows the Langmuir, El-Awady and Temkin isotherms at 35, 45 and 55 °C. PPE is mixed adsorption dominated with physical adsorption at room temperature or with higher PPE concentrations. PPE possesses many polar functional groups such as hydroxyl, carbonyl and hetero-aromatic rings. The inhibition mechanism is closely related to these polar groups, as is the surface coverage of steel.
- Subjects :
- Langmuir
General Chemical Engineering
Chemical structure
Kinetics
02 engineering and technology
010402 general chemistry
01 natural sciences
Corrosion
chemistry.chemical_compound
Corrosion inhibitor
Adsorption
Metal corrosion
Acid corrosion
Electrochemical measurements
Phosphoric acid
QD1-999
technology, industry, and agriculture
General Chemistry
021001 nanoscience & nanotechnology
0104 chemical sciences
Dielectric spectroscopy
Plant extract
Chemistry
chemistry
0210 nano-technology
Renewable inhibitor
Nuclear chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 18785352
- Volume :
- 14
- Issue :
- 5
- Database :
- OpenAIRE
- Journal :
- Arabian Journal of Chemistry
- Accession number :
- edsair.doi.dedup.....1f826352314cabe25adc726e7f5d0d92