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The first 3-fold interpenetrating framework containing both azobenzene-3,3′-dicarboxylicate and 1,2-bis(4-pyridyl)ethylene
- Source :
- Complex Metals: An Open Access Journal, Vol 1, Iss 1, Pp 122-127 (2014)
- Publication Year :
- 2014
- Publisher :
- Informa UK Limited, 2014.
-
Abstract
- The reactions of Co II or Ni II acetate with azobenzene-3,3′-dicarboxylic acid (3,3′-H2AZDB) and 1,2-bis(4-pyridyl)ethylene (bpe) afforded two isomorphic compounds [M 2(3,3′-AZDB)2(bpe)2]n (M=Co (1) and Ni (2)) under hydrothermal conditions. They were characterized by elemental analysis, IR spectra, thermogravimetric analysis and single-crystal X-ray diffraction technique. The structures of compounds 1 and 2 have similar 3-D 3-fold interpenetrating structures in which each 3-D net displayed a 6-connected pcu network consisting of M 2+-AZDB2− layers and bpe pillars. Variable-temperature magnetic-susceptibility measurements revealed the occurrence of weak antiferromagnetic interactions between the Co(II) atoms in 1.
- Subjects :
- Diffraction
Thermogravimetric analysis
α-Polonium cubic network
lcsh:QD71-142
Ethylene
lcsh:Analytical chemistry
Magnetic property
Infrared spectroscopy
General Medicine
Hydrothermal circulation
chemistry.chemical_compound
Crystallography
Azobenzene-3,3′-dicarboxylic acid
Azobenzene
chemistry
Elemental analysis
lcsh:QD901-999
Antiferromagnetism
lcsh:Crystallography
1,2-Bis(4-pyridyl)ethylene
Subjects
Details
- ISSN :
- 2164232X
- Volume :
- 1
- Database :
- OpenAIRE
- Journal :
- Complex Metals
- Accession number :
- edsair.doi.dedup.....22554c65c885c1df8fe8c91bc2e606ad