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Allyl Amination of Phosphinoquinoline Allyl Complexes of Palladium. Influence of the Allyl Hapticity on the Reaction Rate and Regiochemistry

Allyl Amination of Phosphinoquinoline Allyl Complexes of Palladium. Influence of the Allyl Hapticity on the Reaction Rate and Regiochemistry

Authors :
Luciano Canovese
Gavino Chessa
Claudio Santo
Fabiano Visentin
Valerio Bertolasi
Publication Year :
2010

Abstract

The ligands 8-diphenylphosphanylquinoline (DPPQ) and 8-diphenylphosphanyl-2-methylquinoline (DPPQ-Me) react in chlorinated solvents with the allyl dimers [Pd(μ-Cl)(η3-C3H5)]2 and [Pd(μ-Cl)(η3-C3H3M...

Details

Language :
English
Database :
OpenAIRE
Accession number :
edsair.doi.dedup.....22d1d927ff49a0b54adbcbac2bb19737