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Guest-Triggered Aggregation-Induced Emission in Silver Chalcogenolate Cluster Metal-Organic Frameworks
- Source :
- Advanced Science
- Publication Year :
- 2018
-
Abstract
- Utilizing aggregation‐induced emission luminogens (AIEgens) as ligands has proven to be an effective strategy for constructing metal–organic frameworks (MOFs) with intense luminescent properties. However, highly luminescent AIEgen‐based MOFs with adjustable emission properties are rarely achieved because of the rigid conformation of AIEgens in the crystalline state. Here, a dual‐node 3D silver chalcogenolate cluster MOF (1) is designed and synthesized, where the AIE ligand shows relatively flexible and rotatable conformations. The conformations of AIE ligands in 1 are switchable by the absorption/desorption of guest molecules. As a result, 1 exhibited not only intense but also guest molecule switched luminescent properties. More importantly, the switching rate is tunable by using different guest molecules. 1 provides a unique visualized prototype to understand the mechanism of guest‐triggered aggregation‐induced emission in MOFs.
- Subjects :
- Materials science
General Chemical Engineering
General Physics and Astronomy
Medicine (miscellaneous)
02 engineering and technology
010402 general chemistry
Photochemistry
01 natural sciences
Biochemistry, Genetics and Molecular Biology (miscellaneous)
metal–organic frameworks
Desorption
Cluster (physics)
Molecule
General Materials Science
host–guest chemistry
Host–guest chemistry
Ligand
Communication
General Engineering
021001 nanoscience & nanotechnology
Communications
0104 chemical sciences
Metal-organic framework
cluster compounds
crystal transformation
Absorption (chemistry)
0210 nano-technology
Luminescence
aggregation‐induced emission
Subjects
Details
- ISSN :
- 21983844
- Volume :
- 6
- Issue :
- 2
- Database :
- OpenAIRE
- Journal :
- Advanced science (Weinheim, Baden-Wurttemberg, Germany)
- Accession number :
- edsair.doi.dedup.....23bd3aa20f5e48c44938aadf7867a3f7