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Glycosylation study on pradimicin–benanomicin antibiotics
- Source :
- Tetrahedron Letters. 41:6827-6832
- Publication Year :
- 2000
- Publisher :
- Elsevier BV, 2000.
-
Abstract
- In relation to the synthesis of the pradimicin–benanomicin antibiotics, a model study was carried out for introducing the disaccharide moiety. The glycosyl donor 2, prepared from d -glucose and d -xylose, was allowed to react with various glycosyl acceptors in the presence of Cp2HfCl2 and AgClO4. Also studied was the reactivity difference between the conformers of the trans-phenanthrendiol derivatives 12, 13 and 14.
Details
- ISSN :
- 00404039
- Volume :
- 41
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi.dedup.....27410dcf0a930e744606dafde3fd098a