Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br-Mg exchange

Authors :: Taramatee Ramnial
Jason A. C. Clyburne
Stephanie A. Taylor
Charles J. Walsby
Source :: Chemical communications (Cambridge, England). (20)
Publication Year :: 2007
Abstract: Grignard reagents form persistent solutions in phosphonium ionic liquids possessing O-donor anions and these solutions are excellent reaction media for electron transfer processes and transmetallation reactions.

Subjects :: Electron transfer reactions
Inorganic chemistry
Metals and Alloys
Ionic bonding
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
chemistry.chemical_compound
Transmetalation
Electron transfer
chemistry
Reagent
Ionic liquid
Materials Chemistry
Ceramics and Composites
Mg/exchange
Phosphonium

Tools