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Sheets of alternating chirality in the structure of a novel iron(III) complex with a cyclic oxamide ligand
- Source :
- ResearcherID, Scopus-Elsevier
-
Abstract
- An organic–metalloorganic analogue of the inorganic clay minerals has been obtained from the cyclization of N,N′-bis(ethoxalyl)phenylenediamine in basic medium in the presence of iron(III) ions leading to formation of a cyclic oxamide ligand (L). The combination of intramolecular (covalent) interactions between metal and ligand and intermolecular (noncovalent) ionic interactions creates a novel layered compound with an intriguing crystal structure (shown on the right).
Details
- Database :
- OpenAIRE
- Journal :
- ResearcherID, Scopus-Elsevier
- Accession number :
- edsair.doi.dedup.....321a1391359b4c172fb2d83c55adab0d