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A Triflamide-Tethered N-Heterocyclic Carbene-Rhodium(I) Catalyst for Hydroalkoxylation Reactions: Ligand-Promoted Nucleophilic Activation of Alcohols
- Source :
- ChemCatChem, ChemCatChem, 2017, 9 (8), pp.1397-1401. ⟨10.1002/cctc.201601667⟩, ChemCatChem, Wiley, 2017, 9 (8), pp.1397-1401. ⟨10.1002/cctc.201601667⟩
- Publication Year :
- 2017
- Publisher :
- HAL CCSD, 2017.
-
Abstract
- International audience; A triflamide-tethered N-heterocyclic carbene (NHC)-bound Rh-I dicarbonyl catalyst was highly effective for both intermolecular hydroalkoxylation and intramolecular heteroannulation reactions. The involvement of both the amido nitrogen and triflato oxygen atoms of the triflamide functionality for alcohol activation and 1,2-hydrogen shift, respectively, was proposed.
- Subjects :
- ligand design
cyclization
chemistry.chemical_element
Alcohol
010402 general chemistry
alkynes
01 natural sciences
Medicinal chemistry
Catalysis
Rhodium
Inorganic Chemistry
chemistry.chemical_compound
Nucleophile
Organic chemistry
Physical and Theoretical Chemistry
Hydroalkoxylation
Nucleophilic addition
010405 organic chemistry
[CHIM.ORGA]Chemical Sciences/Organic chemistry
Organic Chemistry
[CHIM.CATA]Chemical Sciences/Catalysis
hydroalkoxylation
0104 chemical sciences
nucleophilic addition
chemistry
Intramolecular force
Carbene
Subjects
Details
- Language :
- English
- ISSN :
- 18673899
- Database :
- OpenAIRE
- Journal :
- ChemCatChem, ChemCatChem, 2017, 9 (8), pp.1397-1401. ⟨10.1002/cctc.201601667⟩, ChemCatChem, Wiley, 2017, 9 (8), pp.1397-1401. ⟨10.1002/cctc.201601667⟩
- Accession number :
- edsair.doi.dedup.....3454d0cbb23eb9b602e67d32fecb2a48